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Article Dans Une Revue Chemical Communications Année : 2018

Ruthenium-catalyzed hydrogen isotope exchange of C(sp3)–H bonds directed by a sulfur atom

Résumé

We present here the first example of C(sp3)–H activation directed by a sulfur atom. Based on this transformation catalyzed by Ru/C, we have developed a hydrogen isotope exchange reaction for the deuterium and tritium labelling of thioether substructures in complex molecules.

Domaines

Chimie organique
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Dates et versions

hal-02308831 , version 1 (08-10-2019)

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Longhui Gao, Serge Perato, Sébastien Garcia-Argote, Céline Taglang, Luis Miguel Martinez-Pietro, et al.. Ruthenium-catalyzed hydrogen isotope exchange of C(sp3)–H bonds directed by a sulfur atom. Chemical Communications, 2018, 54 (24), pp.2986-2989. ⟨10.1039/C8CC00653A⟩. ⟨hal-02308831⟩
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