Article Dans Une Revue Inorganic Chemistry Année : 2013

Molecular Tectonics: Control of the Dimensionality in Tetramercaptothiacalixarenes Based Coordination Networks

Résumé

Combinations of tetramercaptotetrathiacalix[4]arene pyridyl appended positional isomers with HgCl2 leads to the formation of neutral coordination networks with their dimensionality imposed by the position of the N atom on the pyridyl group. The ortho isomer leads to the formation of a 1D network, the meta isomer generates a 2D assembly and finally, the para isomer affords a diamond-like 3D coordination architecture.

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hal-02301241 , version 1 (27-11-2020)

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Alexander Ovsyannikov, Sylvie Ferlay, Svetlana E Solovieva, Igor S Antipin, A. I Konovalov, et al.. Molecular Tectonics: Control of the Dimensionality in Tetramercaptothiacalixarenes Based Coordination Networks. Inorganic Chemistry, 2013, 52 (12), pp.6776-6778. ⟨10.1021/ic400899m⟩. ⟨hal-02301241⟩
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