Article Dans Une Revue CrystEngComm Année : 2018

Structural phase diagrams and isomerism inflexible honeycomb-like 2D hydrogen bonded solid solutions

Résumé

Solid solution of Hydrogen bonded networks of formula ((1-2H +)3x(2-2H +)3(1-x)([Fe(CN)6] 3-2)). nH2O, where (1-2H +) and (1-2H +) are bisamidinium H bond donor entities, have been synthetized and structurally analysed. The H bonded systems display a honeycomb-like structure, and depending on the x value, three different pavages of the (6,3) system are observed, leading to three different phases. The precise location of the H bond donor cations (2-2H +) have been performed, evidencing H bonding between adjacent cations. Thermal properties of the solid solutions have been performed.

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hal-02300927 , version 1 (25-11-2020)

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Bo-Wen Hu, Sylvie Ferlay, Nathalie Gruber-Kyritsakas, Mir Wais Hosseini. Structural phase diagrams and isomerism inflexible honeycomb-like 2D hydrogen bonded solid solutions. CrystEngComm, 2018, 20 (13), pp.1853-1861. ⟨10.1039/C8CE00023A⟩. ⟨hal-02300927⟩
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