Structural phase diagrams and isomerism inflexible honeycomb-like 2D hydrogen bonded solid solutions
Résumé
Solid solution of Hydrogen bonded networks of formula ((1-2H +)3x(2-2H +)3(1-x)([Fe(CN)6] 3-2)). nH2O, where (1-2H +) and (1-2H +) are bisamidinium H bond donor entities, have been synthetized and structurally analysed. The H bonded systems display a honeycomb-like structure, and depending on the x value, three different pavages of the (6,3) system are observed, leading to three different phases. The precise location of the H bond donor cations (2-2H +) have been performed, evidencing H bonding between adjacent cations. Thermal properties of the solid solutions have been performed.
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