Precursor-directed synthesis of upconverting LiYF4:Yb3+, Tm3+ nanoparticles and their composites designed for near infra-red driven photocatalysis - Archive ouverte HAL Accéder directement au contenu
Communication Dans Un Congrès Année : 2019

Precursor-directed synthesis of upconverting LiYF4:Yb3+, Tm3+ nanoparticles and their composites designed for near infra-red driven photocatalysis

B. Purohit
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S. Mishra
Benoit Mahler
David Amans
Christophe Dujardin
Yannick Guyot
S. Daniele
G. Ledoux

Résumé

Titanium dioxide (TiO2) and graphitic carbon nitride (g-C3N4) are among the most promising photocatalysts due to their low cost, non-toxicity and high catalytic activity. However, these photocatalysts also have certain limitations in terms of low efficiency of visible light utilization and high recombination rate of the photo-generated electron-hole pairs. Coupling of these photocatalysts with lanthanide-based upconverting nanoparticles (UCNPs) can lead to utilization of near-infrared part of the solar spectrum and, therefore, enhance the photocatalytic efficiency many folds.1 In this context, upconverting nanomaterials LiYF4: Tm3+/Yb3+ have great potential as they show intense upconverted emissions in the deep-UV region,2 which would greatly facilitate efficiency of above photocatalysts. However, in comparison to the more thoroughly investigated NaLnF4-based systems, the studies on upconverting nanomaterials based on the LiYF4 host matrix remain in its nascent state.3 Here we describe bottom-up synthesis of a series of LiYF4 nanocrystals (NCs) co-doped with varying amount of Yb3+ and Tm3+ ions using new molecular precursors [Ln(TFA)3(monoglyme)] [Ln = Y, Tm, Yb] and [Li(TFA)(monoglyme)] (where TFA = trifluoroacetate, and monoglyme = dimethoxyethane). These precursors, synthesized in a simple one-pot reaction and characterized by spectroscopy, single crystal X-ray structures and thermogravimetric studies, are advantageous in terms of being anhydrous. The multicolour up-conversion fluorescence studies of the obtained LiYF4:Tm3+/Yb3+ NCs established them to be promising UC nanophosphors, which were further used to prepare composites with earlier-mentioned photocatalysts to realize near IR-driven photocatalysis. [1] a) S. Wu1, J. Lv, F. Wang, N. Duan, Q. Li, Z. Wang, Sci. Rep., 7, 14435-14746 (2018); b) Y. Chen, S. Mishra, G. Ledoux, E. Jeanneau, M. Daniel, J. Zhang, S. Daniele, Chem. Asian J. 9, 2415‒2421 (2014). [2] V. Mahalingam, F. Vetrone, R. Naccache, A. Speghini, J. A. Capobianco, Adv. Mater., 21, 4025–4028 (2009). [3] T. Cheng, R. Marin, A. Skripka, F. Vetrone, J. Am. Chem. Soc., 140, 12890−12899 (2018).
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Dates et versions

hal-02280196 , version 1 (06-09-2019)

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  • HAL Id : hal-02280196 , version 1

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B. Purohit, S. Mishra, Benoit Mahler, David Amans, Christophe Dujardin, et al.. Precursor-directed synthesis of upconverting LiYF4:Yb3+, Tm3+ nanoparticles and their composites designed for near infra-red driven photocatalysis. The Photoluminescence in Rare Earths: Photonic Materials and Devices (PRE'19), Sep 2019, Nice, France. ⟨hal-02280196⟩
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