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Article Dans Une Revue European Journal of Organic Chemistry Année : 2019

Highly Water-Soluble Amphiphilic Cyclodextrins Bearing Branched and Cyclic Oleic Grafts

Résumé

Amphiphilic β-cyclodextrins bearing various amounts of branched and cyclic oleic grafts are synthetized. The first step of this synthesis is the alkenylation of maleic anhydride by oleic acid derivatives, in the presence of a rhodium catalyst, to produce oleic succinic anhydrides with different ratios of cyclic to branched groups. The second step is the grafting of the oleic succinic anhydrides mixtures on β-cyclodextrin. The obtained cyclodextrins are highly water-soluble and surface active.
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hal-02271385 , version 1 (14-11-2023)

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Aurélien Cocq, Cyril Rousseau, Hervé Bricout, Estefanía Oliva, Véronique Bonnet, et al.. Highly Water-Soluble Amphiphilic Cyclodextrins Bearing Branched and Cyclic Oleic Grafts. European Journal of Organic Chemistry, 2019, 2019 (30), pp.4863-4868. ⟨10.1002/ejoc.201900789⟩. ⟨hal-02271385⟩
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