Synthesis and Viscosimetric Behavior of Poly(acrylamide- co -2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue ACS Omega Année : 2019

Synthesis and Viscosimetric Behavior of Poly(acrylamide- co -2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization

Résumé

High molar masses homopolymers of both acrylamide (AM) and 2-acrylamido-2-methylpropanesulfonate (AMPS) as well as poly(AM-stat-AMPS) exhibiting a large range copolymer composition has been obtained via the optimization of a purely adiabatic gel process. Monomer concentrations ranging from 2.0 to 3.47 M have been successfully tested while keeping the control of the molar masses up to 5 × 106 g mol–1. The products have been characterized in terms of molecular mass and viscosimetric properties
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hal-02187645 , version 1 (06-01-2021)

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Aurora Mejia, Laurent Rodriguez, Charlène Schmitt, Nathalie Andreu, Cédrick Favero, et al.. Synthesis and Viscosimetric Behavior of Poly(acrylamide- co -2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization. ACS Omega, 2019, 4 (6), pp.11119-11125. ⟨10.1021/acsomega.9b00975⟩. ⟨hal-02187645⟩
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