Article Dans Une Revue Acta Crystallographica Section E : Structure Reports Online [2001-2014] Année : 2012

Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate

Résumé

The title compound, (C4H14N2)2[Mo2O4F6]·H2O, was obtained by solvothermal reaction at 443 K for 72 h from a mixture of MoO3, HF, 1,4-diamino­butane (dab), water and ethyl­ene glycol. The structure consists of [Mo2O4F6]4− anionic dimers containing strongly distorted MoO3F3 octa­hedra (with twofold symmetry), diprotonated dab cations and water mol­ecules (twofold symmetry) in the ratio 1:2:1. The cohesion of the three-dimensional structure is ensured through N—H⋯O, N—H⋯F and O—H⋯F inter­actions.

Dates et versions

hal-02173736 , version 1 (04-07-2019)

Identifiants

Citer

J. Lhoste, Annie Hémon-Ribaud, Vincent Maisonneuve, S. Jobic, M. Bujoli-Doeuff. Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate. Acta Crystallographica Section E : Structure Reports Online [2001-2014], 2012, 68 (12), pp.m1520. ⟨10.1107/S1600536812046892⟩. ⟨hal-02173736⟩
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