Nonlinear dielectric constant of nonpolar fluids - Archive ouverte HAL
Article Dans Une Revue The Journal of Chemical Physics Année : 1992

Nonlinear dielectric constant of nonpolar fluids

Résumé

We study the third-order electrical susceptibility of a fluid of nonpolar spherical molecules with linear polarizability and cubic hyperpolarizability. In the electrostatic dipole approximation, we derive an expression for the third-order susceptibility, which allows its evaluation from a property of the linear system. To second order in the linear polarizability, the correction to a mean field approximation, obtained by Buckingham, may be related to the correction to the Clausius-Mossotti formula for the linear dielectric constant. We present numerical results, obtained by computer simulation, for a system of hard spheres.
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Dates et versions

hal-02159857 , version 1 (19-06-2019)

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K. Hinsen, A. Bratz, B. Felderhof. Nonlinear dielectric constant of nonpolar fluids. The Journal of Chemical Physics, 1992, 97 (12), pp.9299-9302. ⟨10.1063/1.463305⟩. ⟨hal-02159857⟩

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