Article Dans Une Revue European Journal of Organic Chemistry Année : 2013

Stereoselective Synthesis of a Bicyclic Norsesquiterpene Backbone - A Possible Route to Nardosinane Derivatives

Résumé

We have developed an efficient diastereoselective synthetic route towards a nardosinane sesquiterpene scaffold. The strategy used a key bicyclic diene intermediate 11a, and allowed access to valuable polyoxygenated sesquiterpenes 21 and 22, which may be regarded as analogues of the natural sesquiterpenes laevinol B and fulvol acetate, respectively.

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hal-02142396 , version 1 (28-05-2019)

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Ouassila Selaimia-Ferdjani, Anirban Kar, Sambhaji P. Chavan, Maxime Horeau, Guillaume Viault, et al.. Stereoselective Synthesis of a Bicyclic Norsesquiterpene Backbone - A Possible Route to Nardosinane Derivatives. European Journal of Organic Chemistry, 2013, 2013 (31), pp.7083-7094. ⟨10.1002/ejoc.201301087⟩. ⟨hal-02142396⟩
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