Organic Salts and Merrifield Resin Supported [PM12O40]3− (M = Mo or W) as Catalysts for Adipic Acid Synthesis - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Molecules Année : 2019

Organic Salts and Merrifield Resin Supported [PM12O40]3− (M = Mo or W) as Catalysts for Adipic Acid Synthesis

Résumé

Adipic acid (AA) was obtained by catalyzed oxidation of cyclohexene, epoxycyclohexane, or cyclohexanediol under organic solvent-free conditions using aqueous hydrogen peroxide (30%) as an oxidizing agent and molybdenum- or tungsten-based Keggin polyoxometalates (POMs) surrounded by organic cations or ionically supported on functionalized Merrifield resins. Operating under these environmentally friendly, greener conditions and with low catalyst loading (0.025% for the molecular salts and 0.001–0.007% for the supported POMs), AA could be produced in interesting yields.

Dates et versions

hal-02140569 , version 1 (27-05-2019)

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Citer

Jana Pisk, Dominique Agustin, Rinaldo Poli. Organic Salts and Merrifield Resin Supported [PM12O40]3− (M = Mo or W) as Catalysts for Adipic Acid Synthesis. Molecules, 2019, 24 (4), pp.783. ⟨10.3390/molecules24040783⟩. ⟨hal-02140569⟩
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