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            <funder>This work was supported by the University of Chicago Materials Research Science and Engineering Center, which is funded by the NSF under award number DMR-1420709, by the NSF under award number CHE-1611331, and by the Defense Advanced Research Projects Agency (DARPA) as a subcontract to Voxtel, Inc. for the Wired program. This work used resources of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357.</funder>
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                <term xml:lang="en">colloidal quantum dots</term>
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              <p>AbstractHgTe colloidal quantum dots (QDs) are of interest because quantum confinement of semimetallic bulk HgTe allows one to synthetically control the bandgap throughout the infrared. Here, we synthesize highly monodisperse HgTe QDs and tune their doping both chemically and electrochemically. The monodispersity of the QDs was evaluated using small-angle X-ray scattering (SAXS) and suggests a diameter distribution of similar to 10% across multiple batches of different sizes. Electron-doped HgTe QDs display an intraband absorbance and bleaching of the first two excitonic features. We see splitting of the intraband peaks corresponding to electronic transitions from the occupied 1Se state to a series of nondegenerate 1Pe states. Spectroelectrochemical studies reveal that the degree of splitting and relative intensity of the intraband features remain constant across doping levels up to two electrons per QD. Theoretical modeling suggests that the splitting of the 1Pe level arises from spin-orbit coupling and reduced QD symmetry. As a result, the fine structure of the intraband transitions is observed in the ensemble studies due to the size uniformity of the as-synthesized QDs and strong spin-orbit coupling inherent to HgTe.</p>
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            <ref type="url">http://www.anl.gov</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-308637" status="INCOMING">
          <orgName>US Department of Energy</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>