The interaction of carbon-centered radicals with copper(I) and copper(II) complexes - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of Coordination Chemistry Année : 2018

The interaction of carbon-centered radicals with copper(I) and copper(II) complexes

Résumé

Although alkylcopper(I) reagents are widespread, compounds containing alkyl ligands on CuII or CuIII are much less common. Such complexes, however, are generated as transient species when carbon-center radicals add to CuI or CuII complexes, respectively, and appear to be involved in several copper-catalyzed organic transformations. A few organocopper(II) and organocopper(III) complexes were found sufficiently robust to allow isolation and full characterization. This article reviews the reactivity of carbon-centered radicals with CuI and CuII ions, both in aqueous and non-aqueous environments, with focus on the importance of the resulting organocopper species on atom transfer radical polymerization and on copper-catalyzed radical termination.
Fichier principal
Vignette du fichier
382-10.1080.00958972.2018.1490416-Accepted.pdf (939.47 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-02129935 , version 1 (01-03-2021)

Identifiants

Citer

Thomas Ribelli, Krzysztof Matyjaszewski, Rinaldo Poli. The interaction of carbon-centered radicals with copper(I) and copper(II) complexes. Journal of Coordination Chemistry, 2018, 71 (11-13), pp.1641-1668. ⟨10.1080/00958972.2018.1490416⟩. ⟨hal-02129935⟩
40 Consultations
188 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More