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              <p>he potentialities in the use of biochars prepared by steam-assisted slow pyrolysis as adsorbents of gases ofstrategic interest (N2,CO2, and CH4) and their mixtures were explored. The biochars prepared fromPopulus nigrawood andcellulosefibers exhibited a narrow microporosity, with average pore sizes ranging between 0.55 and 0.6 nm. The microporevolume increased with the pyrolysis temperature, allowing CO2and CH4uptakes at room temperature between 1.5 and 2.5mmol/g and between 0.1 and 0.5 mmol/g, respectively. These values are in line with those from the literature on biomass-derived carbon-based materials, exhibiting much higher porous features than those reported herein. As for the separation ofCO2/N2and CO2/CH4gas mixtures, data showed that the prepared biochars exhibited good selectivities for CO2over both N2and CH4: between ca. 34 and 119 for a CO2/N2mixture in typical post-combustion conditions (15:85, v/v) and between 14and 34 for a CO2/CH4mixture typical of natural gas upgrading (30:70, v/v)</p>
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