Gas-phase synthesis of lanthanide(III) benzoates Ln(Bz)3 (Ln = La, Tb, Lu) - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Koordinatsionnaya Khimiya / Russian Journal of Coordination Chemistry Année : 2007

Gas-phase synthesis of lanthanide(III) benzoates Ln(Bz)3 (Ln = La, Tb, Lu)

O. Kotova
  • Fonction : Auteur
V. Utochnikova
  • Fonction : Auteur
Svetlana V. Eliseeva
V. Samoilenkov
  • Fonction : Auteur
N. Kuz’mina
  • Fonction : Auteur

Résumé

A new method for the synthesis and film deposition of nonvolatile aromatic lanthanide(III) carboxylates by li.-and exchange reaction between the starting volatile components in the gas phase was proposed. The complexes Ln(BZ)(3) (Ln = La3+, Tb3+, Lu3+; HBz = benzoic acid) were synthesized by gas-phase ligand exchange reaction between the volatile Ln(Thd)(3) and HBz (HThd = 2,2,6,6-tetramethylheptane-3,5-dione). The composition of the complexes was confirmed by elemental, thermal, IR-spectroscopic, and photoluminescence analyses and, in the case of lanthanum and lutetium complexes, by H-1 NMR.

Domaines

Chimie

Dates et versions

hal-02103410 , version 1 (18-04-2019)

Identifiants

Citer

O. Kotova, V. Utochnikova, Svetlana V. Eliseeva, V. Samoilenkov, N. Kuz’mina. Gas-phase synthesis of lanthanide(III) benzoates Ln(Bz)3 (Ln = La, Tb, Lu). Koordinatsionnaya Khimiya / Russian Journal of Coordination Chemistry, 2007, 33 (6), pp.454-457. ⟨10.1134/S1070328407060115⟩. ⟨hal-02103410⟩
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