Influence of heteroligand complexation on the thermal, photoluminescent, and film-forming properties of some aromatic terbium(III) carboxylates - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Koordinatsionnaya Khimiya / Russian Journal of Coordination Chemistry Année : 2006

Influence of heteroligand complexation on the thermal, photoluminescent, and film-forming properties of some aromatic terbium(III) carboxylates

O. Kotova
  • Fonction : Auteur
Svetlana V. Eliseeva
A. Volosnikov
  • Fonction : Auteur
A. Oleinikov
  • Fonction : Auteur
S. Lepnev
  • Fonction : Auteur
A. Vitukhnovskii
  • Fonction : Auteur
N. Kuz’mina
  • Fonction : Auteur

Résumé

With homoligand TbL3 and heteroligand complexes TbL3(Q)n (HL = HSal (salicylic acid) and HPA (2-anilinobenzoic acid); Q = TPPO (triphenylphosphine oxide) and TOPO (tri(n-octyl)phosphine oxide); n = 1 or 2) as examples, it was shown that heteroligand complexation affects not only the thermal and photoluminescent properties but also the quality of films obtained by centrifugation: the root-mean-square roughness changes in the order TbL3Q > TbL3(Q)2 ≈ TbL3. This is due to different association degrees of the complexes in solution, which was confirmed by MALDI-TOF MS data.

Domaines

Chimie

Dates et versions

hal-02103402 , version 1 (18-04-2019)

Identifiants

Citer

O. Kotova, Svetlana V. Eliseeva, A. Volosnikov, A. Oleinikov, S. Lepnev, et al.. Influence of heteroligand complexation on the thermal, photoluminescent, and film-forming properties of some aromatic terbium(III) carboxylates. Koordinatsionnaya Khimiya / Russian Journal of Coordination Chemistry, 2006, 32 (12), pp.901-909. ⟨10.1134/S1070328406120086⟩. ⟨hal-02103402⟩
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