<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-02102543</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-04T19:26:49+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Factors affecting the reactivity of zinc oxide with different drying oils: a vibrational spectroscopy study</title>
            <author role="aut">
              <persName>
                <forename type="first">Francesca</forename>
                <surname>Casadio</surname>
              </persName>
              <idno type="halauthorid">1123786-0</idno>
              <affiliation ref="#struct-558181"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Ludovic</forename>
                <surname>Bellot-Gurlet</surname>
              </persName>
              <email type="md5">127024ddc0c281256d975914b10aeb9b</email>
              <email type="domain">sorbonne-universite.fr</email>
              <ptr type="url" target="https://www.monaris.cnrs.fr/contact/ludovic-bellot-gurlet/"/>
              <idno type="idhal" notation="string">ludovic-bellot-gurlet</idno>
              <idno type="idhal" notation="numeric">12937</idno>
              <idno type="halauthorid" notation="string">1716-12937</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/G-7132-2012</idno>
              <idno type="IDREF">https://www.idref.fr/168523167</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-7995-6261</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/G-7132-2012</idno>
              <affiliation ref="#struct-247183"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Céline</forename>
                <surname>Paris</surname>
              </persName>
              <email type="md5">32aa998180839c2be6288448efedc90d</email>
              <email type="domain">upmc.fr</email>
              <idno type="idhal" notation="numeric">926767</idno>
              <idno type="halauthorid" notation="string">401134-926767</idno>
              <affiliation ref="#struct-247183"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Ludovic</forename>
                <surname>Bellot-Gurlet</surname>
              </persName>
              <email type="md5">127024ddc0c281256d975914b10aeb9b</email>
              <email type="domain">sorbonne-universite.fr</email>
            </editor>
            <funder ref="#projanr-26414"/>
            <funder>This work was partly supported by the LabEx MiChem part of French state funds managed by the ANR within the Investissements d'Avenir programme under reference ANR-11-IDEX-0004-02</funder>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2019-04-17 14:28:41</date>
              <date type="whenModified">2025-08-12 17:08:18</date>
              <date type="whenReleased">2019-04-17 14:28:41</date>
              <date type="whenProduced">2019-03-24</date>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="130880">
                <persName>
                  <forename>Ludovic</forename>
                  <surname>Bellot-Gurlet</surname>
                </persName>
                <email type="md5">127024ddc0c281256d975914b10aeb9b</email>
                <email type="domain">sorbonne-universite.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-02102543</idno>
            <idno type="halUri">https://hal.science/hal-02102543</idno>
            <idno type="halBibtex">casadio:hal-02102543</idno>
            <idno type="halRefHtml">Francesca Casadio; Katrien Keune; Petria Noble; Annelies van Loon; Ella Hendriks; Silvia A. Centeno; Gillian Osmond. &lt;i&gt;Metal soaps in Art. Conservation and research&lt;/i&gt;, Springer, pp.153-170, 2019, 978-3-319-90616-4. &lt;a target="_blank" href="https://dx.doi.org/10.1007/978-3-319-90617-1_9"&gt;&amp;#x27E8;10.1007/978-3-319-90617-1_9&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Francesca Casadio; Katrien Keune; Petria Noble; Annelies van Loon; Ella Hendriks; Silvia A. Centeno; Gillian Osmond. Metal soaps in Art. Conservation and research, Springer, pp.153-170, 2019, 978-3-319-90616-4. &amp;#x27E8;10.1007/978-3-319-90617-1_9&amp;#x27E9;</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="MONARIS" corresp="SORBONNE-UNIVERSITE">De la Molécule aux Nanos-objets : Réactivité, Interactions et Spectroscopies</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="MICHEM" corresp="SORBONNE-UNIVERSITE">Labex MiChem</idno>
            <idno type="stamp" n="SORBONNE-UNIVERSITE">Sorbonne Université</idno>
            <idno type="stamp" n="SORBONNE-UNIV" corresp="SORBONNE-UNIVERSITE">Sorbonne Université 01/01/2018</idno>
            <idno type="stamp" n="SU-SCIENCES" corresp="SORBONNE-UNIVERSITE">Faculté des Sciences de Sorbonne Université</idno>
            <idno type="stamp" n="TEST-HALCNRS">Collection test HAL CNRS</idno>
            <idno type="stamp" n="ANR">ANR</idno>
            <idno type="stamp" n="ALLIANCE-SU"> Alliance Sorbonne Université</idno>
            <idno type="stamp" n="TEST2-HALCNRS">TEST2-HALCNRS</idno>
            <idno type="stamp" n="CHIMIE-SU" corresp="SORBONNE-UNIVERSITE">UFR de Chimie de Sorbonne-Université</idno>
            <idno type="stamp" n="SUPRA_PHYS_CHIMIE">Physico-Chimie</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Factors affecting the reactivity of zinc oxide with different drying oils: a vibrational spectroscopy study</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Francesca</forename>
                    <surname>Casadio</surname>
                  </persName>
                  <idno type="halauthorid">1123786-0</idno>
                  <affiliation ref="#struct-558181"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Ludovic</forename>
                    <surname>Bellot-Gurlet</surname>
                  </persName>
                  <email type="md5">127024ddc0c281256d975914b10aeb9b</email>
                  <email type="domain">sorbonne-universite.fr</email>
                  <ptr type="url" target="https://www.monaris.cnrs.fr/contact/ludovic-bellot-gurlet/"/>
                  <idno type="idhal" notation="string">ludovic-bellot-gurlet</idno>
                  <idno type="idhal" notation="numeric">12937</idno>
                  <idno type="halauthorid" notation="string">1716-12937</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/G-7132-2012</idno>
                  <idno type="IDREF">https://www.idref.fr/168523167</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-7995-6261</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/G-7132-2012</idno>
                  <affiliation ref="#struct-247183"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Céline</forename>
                    <surname>Paris</surname>
                  </persName>
                  <email type="md5">32aa998180839c2be6288448efedc90d</email>
                  <email type="domain">upmc.fr</email>
                  <idno type="idhal" notation="numeric">926767</idno>
                  <idno type="halauthorid" notation="string">401134-926767</idno>
                  <affiliation ref="#struct-247183"/>
                </author>
              </analytic>
              <monogr>
                <idno type="isbn">978-3-319-90616-4</idno>
                <title level="m">Metal soaps in Art. Conservation and research</title>
                <editor>Francesca Casadio</editor>
                <editor>Katrien Keune</editor>
                <editor>Petria Noble</editor>
                <editor>Annelies van Loon</editor>
                <editor>Ella Hendriks</editor>
                <editor>Silvia A. Centeno</editor>
                <editor>Gillian Osmond</editor>
                <imprint>
                  <publisher>Springer</publisher>
                  <pubPlace>Cham</pubPlace>
                  <biblScope unit="pp">153-170</biblScope>
                  <date type="datePub">2019-03-24</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1007/978-3-319-90617-1_9</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">Artificial aging</term>
                <term xml:lang="en">Zinc carboxylates</term>
                <term xml:lang="en">Drying oils</term>
                <term xml:lang="en">ATR-FTIR</term>
                <term xml:lang="en">Infrared spectroscopy</term>
                <term xml:lang="en">Humidity</term>
                <term xml:lang="en">Linseed oil</term>
                <term xml:lang="en">Tung oil</term>
                <term xml:lang="en">Stand oil</term>
                <term xml:lang="en">Alkyd</term>
                <term xml:lang="en">Metal soaps</term>
              </keywords>
              <classCode scheme="halDomain" n="chim.anal">Chemical Sciences/Analytical chemistry</classCode>
              <classCode scheme="halTypology" n="COUV">Book sections</classCode>
              <classCode scheme="halOldTypology" n="COUV">Book sections</classCode>
              <classCode scheme="halTreeTypology" n="COUV">Book sections</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>This study focuses on the short-term reactivity of zinc oxide with different types of drying oils. Chemical grade zinc oxide (with diameter &lt;100 nm) was mixed with oils with different proportions and types of fatty acids. Specifically, reactivity of zinc oxide with alkali-refined linseed oil, raw linseed oil, boiled linseed oil, polymerized linseed oil, stand oil, tung oil, and alkyd was studied between 4 days and 10 months. Effects of short-term exposure to temperature, humidity, and pH were also evaluated. The type of metal soaps formed and the kinetics of formation were monitored with attenuated total reflection Fourier transform infrared (ATR- FTIR) spectroscopy. The results confirm that humidity and heat combined favor the formation of both network-coordinated zinc carboxylates (POL-Zn) and zinc complexes of free fatty acids (FA-Zn) irrespective of the type of oil; however, the phenomenon is particularly severe for alkali-refined, raw, and boiled linseed oils, while stand oil and tung oil show the lowest amounts of zinc soap (FA-Zn) formation. The findings advance our knowledge of the reactivity of zinc oxide with an expanded range of drying oils that are commonly encountered in many nineteenth- and twentieth-century paints and reinforce the notion that even short-term exposure to heat with humidity can have irreversible effects on zinc carboxylate formation.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="institution" xml:id="struct-558181" status="VALID">
          <idno type="ROR">https://ror.org/03kyqs312</idno>
          <orgName>The Art Institute of Chicago</orgName>
          <orgName type="acronym">AIC</orgName>
          <desc>
            <address>
              <addrLine>111 South Michigan AvenueChicago, IL 60603</addrLine>
              <country key="US"/>
            </address>
            <ref type="url">https://www.artic.edu/</ref>
          </desc>
        </org>
        <org type="laboratory" xml:id="struct-247183" status="OLD">
          <idno type="RNSR">201420764N</idno>
          <idno type="ROR">https://ror.org/02jkg8m11</idno>
          <orgName>De la Molécule aux Nanos-objets : Réactivité, Interactions et Spectroscopies</orgName>
          <orgName type="acronym">MONARIS</orgName>
          <date type="start">2014-01-01</date>
          <date type="end">2017-12-31</date>
          <desc>
            <address>
              <addrLine>Université Pierre et Marie CURIE Bâtiment F 4, place Jussieu - 75252 PARIS Cedex 05</addrLine>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-93591" type="direct"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR8233" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-93591" status="OLD">
          <idno type="ROR">https://ror.org/02en5vm52</idno>
          <orgName>Université Pierre et Marie Curie - Paris 6</orgName>
          <orgName type="acronym">UPMC</orgName>
          <date type="end">2017-12-31</date>
          <desc>
            <address>
              <addrLine>4 place Jussieu - 75005 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.upmc.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
      </listOrg>
      <listOrg type="projects">
        <org type="anrProject" xml:id="projanr-26414" status="VALID">
          <idno type="anr">ANR-11-IDEX-0004</idno>
          <orgName>SUPER</orgName>
          <desc>Sorbonne Universités à Paris pour l'Enseignement et la Recherche</desc>
          <date type="start">2011</date>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>