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Article Dans Une Revue Polymer Année : 2009

Synthesis and characterization of a methacrylic polyelectrolyte capable of reacting with primary amines at room temperature in water

Résumé

The synthesis of a water-soluble ionic methacrylate monomer containing a sodium 4-hydroxy- benzenesulfonate reactive blocked isocyanate is described. The optimized synthetic procedure is fast and easy to use, yielding a monomer of high purity and in good yields. An investigation of the hydrolytic stability of this electrophilic reagent indicated that it could be stored under reasonable conditions. A polyelectrolyte exhibiting the pendant reactive functionalities as side groups was obtained by free- radical polymerization. The obtained polymer exhibited excellent reactivity toward a primary aliphatic amine in water at room temperature, supporting the possible use of this monomer in the bioconjugation area.
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hal-02090390 , version 1 (04-04-2019)

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Julien Barruet, Romain Molle, Julien Babinot, Jacques Penelle. Synthesis and characterization of a methacrylic polyelectrolyte capable of reacting with primary amines at room temperature in water. Polymer, 2009, 50 (11), pp.2335-2340. ⟨10.1016/j.polymer.2009.03.038⟩. ⟨hal-02090390⟩

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