Tunable P‐Stereogenic P,N‐Phosphine Ligands Design: Synthesis and Coordination Chemistry to Palladium
Résumé
The synthesis of P,N heterobidentate phosphine / palladium complexes has been realized from P-stereogenic enantiopure ligands. Five, six or seven membered ring complexes have been fully characterized, notably by X-ray diffraction, allowing the study of the chelation to a "palladium (II) dichloride" unit. The nature of nitrogen coordination site as well as the size of the ring modify the bite-angle at the solid state.
| Origine | Fichiers produits par l'(les) auteur(s) |
|---|
Loading...