Emergent chirality in achiral liquid crystals: insights from molecular simulation models of the behaviour of bent-core mesogens - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Liquid Crystals Année : 2018

Emergent chirality in achiral liquid crystals: insights from molecular simulation models of the behaviour of bent-core mesogens

Résumé

We report insights into the behaviour of achiral bent-core liquid crystals using (a) atomistic models of the PnOPIMB series of mesogens and (b) simple coarse-grained models that demonstrate the spontaneous transfer of chirality between molecules by preferential selection of chiral conformations. The models explain the unusual phenomena that chiral interactions can lead to an increase in chirality (decrease in pitch) of a bulk cholesteric liquid crystal when doped with an achiral material. We demonstrate also that chiral interactions are sufficiently strong to induce nanophase separation of an achiral mesogen within a liquid crystal phase, into nanodomains of opposite handedness by preferential selection of conformations that are instantaneously chiral (i.e. nanophase separation of R and S conformations of a molecule that is strictly achiral). We suggest that this unusual behaviour contributes to the templating of chiral structures in bulk phases and, hence, to many of the extraordinary properties of bent-core mesogens that include the formations of helical nanofilaments and the chiral dark conglomerate phase.
Fichier principal
Vignette du fichier
LintuvuoriLC2018.pdf (2.61 Mo) Télécharger le fichier
Origine : Publication financée par une institution
Loading...

Dates et versions

hal-02068218 , version 1 (14-03-2019)

Identifiants

Citer

Juho S. Lintuvuori, Gary Yu, Martin Walker, Mark R Wilson. Emergent chirality in achiral liquid crystals: insights from molecular simulation models of the behaviour of bent-core mesogens. Liquid Crystals, 2018, 45 (13-15), pp.1996-2009. ⟨10.1080/02678292.2018.1492037⟩. ⟨hal-02068218⟩

Collections

CNRS LOMA
14 Consultations
98 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More