2D 7 Li Ultrafast CT-COSY: a new tool for the rapid measurement of tiny homonuclear lithium scalar couplings - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2017

2D 7 Li Ultrafast CT-COSY: a new tool for the rapid measurement of tiny homonuclear lithium scalar couplings

Résumé

The measurement of small homonuclear 2J7Li–7Li scalar couplings relying on constant time (CT) COSY NMR suffers from strong time limitations. We describe the first Ultrafast CT COSY experiment on lithium 7, which provides a considerable acceleration in the study of the aggregation state and dynamics of n-BuLi/MeLi complexes.

Domaines

Chimie organique
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Dates et versions

hal-02019169 , version 1 (14-02-2019)

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Citer

Ghanem Hamdoun, B. Gouilleux, Muriel Sebban, Gabriella Barozzino-Consiglio, Anne Harrison-Marchand, et al.. 2D 7 Li Ultrafast CT-COSY: a new tool for the rapid measurement of tiny homonuclear lithium scalar couplings. Chemical Communications, 2017, 53 (1), pp.220-223. ⟨10.1039/c6cc08744b⟩. ⟨hal-02019169⟩
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