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Article Dans Une Revue European Journal of Inorganic Chemistry Année : 2014

Functionalisable N-heterocyclic carbene–triazole palladium complexes and their application in the suzuki–miyaura reaction

Résumé

Seven functionalised N-heterocyclic carbene (NHC) ligands and their corresponding palladium(II) complexes have been synthesised with a triazole moiety as a modular and stable linkage between the catalytic centre and the secondary functional group. The complexes were prepared in good yields and fully characterised by NMR spectroscopy, mass spectrometry and X-ray crystallography. The complexes are active in the Suzuki–Miyaura cross-coupling reaction, with catalytic activities maintained whatever the triazolyl substituent. This opens the possibility for various functionalisations of NHC–palladium complexes.

Dates et versions

hal-02007969 , version 1 (05-02-2019)

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Citer

G. Gogolieva, H. Bonin, J. Durand, Odile Dechy-Cabaret, E. Gras. Functionalisable N-heterocyclic carbene–triazole palladium complexes and their application in the suzuki–miyaura reaction. European Journal of Inorganic Chemistry, 2014, 2014 (12), pp.2088-2094. ⟨10.1002/ejic.201301607⟩. ⟨hal-02007969⟩
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