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Article Dans Une Revue European Journal of Inorganic Chemistry Année : 2014

Slow exchange of bidentate ligands between rhodium(I) complexes: Evidence of both neutral and anionic ligand exchange

Résumé

The phosphine double exchange process involving [RhCl(COD)(TPP)] and [Rh(acac)(CO)(TMOPP)] (TPP = PPh3, TMOPP = P(C6H4-4-OMe)(3)) to yield [RhCl(COD)(TMOPP)] and [Rh(acac)(CO)(TPP)] is very rapid but is followed by a much slower process where the bidentate ligands are exchanged to yield [Rh(acac)(COD)] and a mixture of [RhCl(CO)(TPP)(2)], [RhCl(CO)(TMOPP)(2)], and [RhCl(CO)(TPP)(TMOPP)]. The exchange involving [RhCl(COD)(L)] and [Rh(acac)(CO)(L)] yields [Rh(acac)(COD)] and [RhCl(CO)(L)(2)], where the reaction is much faster when L = TPP than when L = TMOPP. The mixed-metal system comprising [IrCl(COD)(TPP)] and [Rh(acac)(CO)(TPP)] yields all four complexes [M(acac)(COD)] and [MCl(CO)(TPP)(2)], where M = Rh and Ir. This illustrates that both a neutral ligand exchange and an anionic ligand exchange occur. Possible pathways for these processes are discussed.
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Dates et versions

hal-02007940 , version 1 (29-07-2021)

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Si Chen, E. Manoury, Rinaldo Poli. Slow exchange of bidentate ligands between rhodium(I) complexes: Evidence of both neutral and anionic ligand exchange. European Journal of Inorganic Chemistry, 2014, 34, pp.5820-5826. ⟨10.1002/ejic.201402810⟩. ⟨hal-02007940⟩
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