Arsagermene, a compound with an –As=Ge–(R1;R2) double bond - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2018

Arsagermene, a compound with an –As=Ge–(R1;R2) double bond

Résumé

The first compound featuring an As=Ge double bond, arsagermene Mes*As=Ge(SiMetBu2)2, was synthesized, isolated and fully characterized. Crystallographic studies revealed that arsagermene has a planar Ge=As bond of 2.2731(8) Å, which is notably shorter than the standard Ge–As single bond. The double bond character of arsagermene was further supported by computational data.
Fichier non déposé

Dates et versions

hal-01963523 , version 1 (21-12-2018)

Identifiants

Citer

Vladimir Ya Lee, Manami Kawai, Olga A. Gapurenko, V. I. Minkin, Heinz Gornitzka, et al.. Arsagermene, a compound with an –As=Ge–(R1;R2) double bond. Chemical Communications, 2018, 54 (78), pp.10947-10949. ⟨10.1039/C8CC05630G⟩. ⟨hal-01963523⟩
25 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More