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Article Dans Une Revue Molecules Année : 2018

Novel methinic functionalized and dendritic C-scorpionates

Résumé

The study of chelating ligands is undoubtedly one of the most significant fields of research in chemistry. The present work is directed to the synthesis of new functionalized derivatives of tripodal C-scorpionate compounds. Tris-2,2,2-(1-pyrazolyl)ethanol, HOCH2C(pz)3 (1), one of the most important derivatives of hydrotris(pyrazolyl)methane, was used as a building block for the synthesis of new functionalized C-scorpionates, aiming to expand the scope of this unexplored class of compounds. The first dendritic C-scorpionate was successfully prepared and used in the important industrial catalytic reactions, Sonogashira and Heck C-C cross-couplings.

Dates et versions

hal-01957978 , version 1 (17-12-2018)

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Luisa Martins, R. Wanke, Telma Silva, Armando Pombeiro, Paul Servin, et al.. Novel methinic functionalized and dendritic C-scorpionates. Molecules, 2018, 23 (12), pp.3066. ⟨10.3390/molecules23123066⟩. ⟨hal-01957978⟩
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