Coordination chemistry of neutral mono-oxide, sulfide and selenide bis(diphenylphosphino)amine (DPPA)-based ligands and their N-substituted/functionalized derivatives - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Coordination Chemistry Reviews Année : 2018

Coordination chemistry of neutral mono-oxide, sulfide and selenide bis(diphenylphosphino)amine (DPPA)-based ligands and their N-substituted/functionalized derivatives

Résumé

This review provides a summary, including spectroscopic and structural data, of the metal complexes accessible with mono-oxide, sulfide and selenide bis(diphenylphosphino)amine (DPPA)-based ligands and their N-substituted/functionalized derivs. The nature of the E (O, S, Se) donor in these mixed P,P=E donor ligands strongly influences the nature of the resulting metal complexes, which can incorporate the DPPA-type ligand(s) as P-monodentate or P,E-chelate. When available, a comparison between the reactivity of the mixed P,P=E and parent P,P systems is given. The catalytic applications of P,E-supported metal complexes are also discussed.
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hal-01954090 , version 1 (01-03-2021)

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Christophe Fliedel, Rinaldo Poli. Coordination chemistry of neutral mono-oxide, sulfide and selenide bis(diphenylphosphino)amine (DPPA)-based ligands and their N-substituted/functionalized derivatives. Coordination Chemistry Reviews, 2018, 355, pp.1-26. ⟨10.1016/j.ccr.2017.07.010⟩. ⟨hal-01954090⟩
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