Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes - Archive ouverte HAL Access content directly
Journal Articles Chemical Communications Year : 2018

Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes

Abstract

IMes-derived thioureas in which the imidazolyl ring is directly substituted by one or two dimethylamino groups are redox-active, exhibiting one and two oxidized states, respectively. The structure, stability, and electronics of the oxidized species are investigated, emphasizing the decisive role of the amino substituents.
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hal-01948412 , version 1 (07-12-2018)

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Mirko Ruamps, S. Bastin, Lionel Rechignat, Alix Sournia-Saquet, Dmitry A. Valyaev, et al.. Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes. Chemical Communications, 2018, 54 (55), pp.7653-7656. ⟨10.1039/C8CC03934H⟩. ⟨hal-01948412⟩
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