Exfoliation of Hexagonal Boron Nitride (h-BN) in Liquide Phase by Ion Intercalation - Archive ouverte HAL
Article Dans Une Revue Nanomaterials Année : 2018

Exfoliation of Hexagonal Boron Nitride (h-BN) in Liquide Phase by Ion Intercalation

Résumé

A green approach to prepare exfoliated hexagonal boron nitride nanosheets (h-BNNS) from commercially pristine h-BN involving a two-step procedure was investigated. The first step involves the dispersion of pristine h-BN within an aqueous solution containing gelatin and potassium or zinc chloride using a sonication method. The second involves the removal of larger exfoliated h-BNNS through a centrifugation procedure. The exfoliation was caused not only by the sonication effect but also by intercalation of K+ and Zn2+ ions. Transmission electronic microscopy, X-ray diffraction and Raman spectroscopy techniques show that the obtained h-BNNS generally display a thickness of about a few (2-3) layers with an exfoliation efficiency as high as 16.3 +/- 0.4%.
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hal-01926507 , version 1 (19-11-2018)

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Danae Gonzalez Ortiz, Céline Pochat-Bohatier, Julien Cambedouzou, Mikhael Bechelany, Philippe Miele. Exfoliation of Hexagonal Boron Nitride (h-BN) in Liquide Phase by Ion Intercalation. Nanomaterials, 2018, 8 (9), pp.716. ⟨10.3390/nano8090716⟩. ⟨hal-01926507⟩
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