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Article Dans Une Revue Turkish Journal of Chemistry Année : 2015

Contribution of heterobifunctional ligands to transition metal-catalysed C-C coupling reactions

Résumé

In this account the authors' latest results in C-C coupling catalysis are reviewed. First, an efficient catalytic system for the Kumada Tamao Corriu coupling reaction based on NHC-phosphine (NHC = N-heterocyclic carbene) nickel complexes is presented. Then the use of palladium complexes of chiral ferrocenyl NHC-phosphines in the asymmetric Suzuki-Miyaura coupling reaction is reported. High catalytic activities and moderate enantioselectivities (cc up to 46%) were obtained. Chiral ferrocenyl phosphine ethers were also tested in the asymmetric Suzuki-Miyaura reaction yielding good activities and moderate enantioselectivities (cc up to 37%). Finally, the original synthesis of a ferrocenyl rhodium(III) complex and its successful use as catalyst for a C-C coupling reaction via C-H activation of 2-phenylpyridine is presented.

Dates et versions

hal-01919615 , version 1 (12-11-2018)

Identifiants

Citer

A. Labande, Éric Deydier, E. Manoury, Jean-Claude Daran, Catherine Audin, et al.. Contribution of heterobifunctional ligands to transition metal-catalysed C-C coupling reactions. Turkish Journal of Chemistry, 2015, 39 (6), pp.1158-1170. ⟨10.3906/kim-1507-73⟩. ⟨hal-01919615⟩
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