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              <p>Our understanding of hydrological and chemical processes at the catchment scale is limited by our capacity to record the full breadth of the information carried by river chemistry,  both  in  terms  of  sampling  frequency  and  precision. Here, we present a proof-of-concept study of a “lab in the field” called the “River Lab” (RL), based on the idea of permanently  installing  a  suite  of  laboratory  instruments  in the field next to a river. Housed in a small shed, this set of instruments performs analyses at a frequency of one every 40 min for major dissolved species (Na+ , K+, g2+, Ca 2+,Cl − , SO2 − 4 , NO−3) through continuous sampling and filtration of the river water using automated ion chromatographs. The RL was deployed in the Orgeval Critical Zone Observatory, France for over a year of continuous analyses. Results show that the RL is able to capture long-term fine chemical variations with no drift and a precision significantly better than conventionally achieved in the laboratory (up to ±0.5 % for  all  major  species  for  over  a  day  and  up  to  1.7 %  over 2  months).  The  RL  is  able  to  capture  the  abrupt  changes in  dissolved  species  concentrations  during  a  typical  6-day rain event, as well as daily oscillations during a hydrological low-flow period of summer drought. Using the measured signals as a benchmark, we numerically assess the effects of a lower sampling frequency (typical of conventional field sampling campaigns) and of a lower precision (typically reached in  the  laboratory)  on  the  hydrochemical  signal.  The  high-resolution,  high-precision  measurements  made  possible  by the RL open new perspectives for understanding critical zone hydro-bio-geochemical cycles. Finally, the RL also offers a solution for management agencies to monitor water quality in quasi-real time.</p>
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