Article Dans Une Revue Angewandte Chemie International Edition Année : 2010

Controlled Reducibility of a Metal-Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption

Ji Woong Yoon
  • Fonction : Auteur
Young Kyu Hwang
  • Fonction : Auteur
Marco Daturi
Christian Serre
Alirio E Rodrigues
  • Fonction : Auteur

Résumé

Gas grabber: Reduction of the porous metal–organic framework MIL-100(Fe) (see picture; X−: OH− or F−; red: O of trimesate ligands) to form coordinatively unsaturated sites at iron(II) (depicted as a violet circle) is essential for selective gas purification or the selective removal of unsaturated gas impurities.

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Dates et versions

hal-01840500 , version 1 (16-07-2018)

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Ji Woong Yoon, You-Kyong Seo, Young Kyu Hwang, Jong-San Chang, Herve Leclerc, et al.. Controlled Reducibility of a Metal-Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption. Angewandte Chemie International Edition, 2010, 49 (34), pp.5949-5952. ⟨10.1002/anie.201001230⟩. ⟨hal-01840500⟩
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