Mesoporous ZSM-22 zeolite (TON structure) is prepared by controlled silicon extraction in aqueous NaOH under different conditions of concentration, temperature, and time. The first challenge is to synthesize a pure ZSM-22 sample, since ZSM-5 and cristobalite impurities are hard to avoid. For this purpose, hydrothermal syntheses in autoclaves of 30-1000 cm(3) using tumbling or magnetic mixing were conducted. The parent (calcined) and alkaline-treated samples are characterised by XRD, AAS, N(2) and Ar adsorption, TEM, (27)Al MAS NMR, and FTIR. The introduction of mesoporosity in ZSM-22 crystals is not straightforward due to their peculiar characteristics: the rod-like morphology of their small crystallites, the one-dimensionality of the ellipsoidal micropore system, and an uneven Al distribution. Compared to other zeolite frameworks such as MFI, the generation of up to 95 m(2) g(-1) of (both inter-and intracrystalline) mesopore surface area by NaOH treatment leads to a sizeable drop of the micropore volume (down to 0.006 cm(3) g(-1)), attributed to blocking by re-deposited Al species. A subsequent mild acid treatment in aqueous HCl restores ca. 90% of the original micropore volume and increases the mesopore surface area to 114 m(2) g(-1). However, due to the particular Al distribution in the parent ZSM-22 crystals, only 37% of the original Bronsted acidity is recovered. A new descriptor `desilication efficiency' is introduced to relate the mesopore area generated to the mass of zeolite dissolved. In the case of ZSM-22 nanorods and ferrierite platelets, the desilication efficiency is relatively low compared to ZSM-5, most likely due to the crystal morphology of the former two zeolites. The auxiliary mesoporosity developed in ZSM-22 brings new prospects to catalytic applications of the zeolite due to the extensive creation of pore mouths in the hierarchical sample.