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Article Dans Une Revue Chemical Communications Année : 2015

Direct accessibility of mixed-metal (III/II) acid sites through the rational synthesis of porous metal carboxylates

Résumé

The scalable and environmentally-friendly synthesis of mixed Fe(III)/M(II) (M = Ni, Co, Mg) polycarboxylate porous MOFs based on the Secondary Building Unit approach is reported. A combination of in situ infrared spectroscopy, 57Fe Mössbauer spectrometry and adsorption microcalorimetry confirms the direct accessibility of the iron(III) and metal(II) sites under low temperature activation conditions.

Domaines

Chimie

Dates et versions

hal-01840207 , version 1 (16-07-2018)

Identifiants

Citer

S. Wongsakulphasatch, F. Nouar, J. Rodriguez, L. Scott, Clément Leguillouzer, et al.. Direct accessibility of mixed-metal (III/II) acid sites through the rational synthesis of porous metal carboxylates. Chemical Communications, 2015, 50 (51), pp.10194--10197. ⟨10.1039/C5CC02550H⟩. ⟨hal-01840207⟩
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