Cis,cis,cis,cis-1,2,3,4,5-Pentakis(hydroxymethyl)cyclopentane - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Tetrahedron Année : 2013

Cis,cis,cis,cis-1,2,3,4,5-Pentakis(hydroxymethyl)cyclopentane

Résumé

All-cis pentamethanolcyclopentane has been obtained in six steps by Diels–Alder condensation of maleic anhydride with (benzyloxymethyl)cyclopenta-2,4-diene, reduction of the anhydride to a diol that was protected as the acetonide. Then, ozonolysis of the double bond, followed by reduction led to a cis-diol. Then successive deprotections of the three other methanol groups gave the cis,cis,cis,cis-1,2,3,4,5-pentakis(hydroxymethyl)cyclopentane.

Domaines

Chimie
Fichier non déposé

Dates et versions

hal-01798178 , version 1 (23-05-2018)

Identifiants

Citer

Adeline Pujol, Nicolas Ratel-Ramond, André Gourdon. Cis,cis,cis,cis-1,2,3,4,5-Pentakis(hydroxymethyl)cyclopentane. Tetrahedron, 2013, 69 (43), pp.9139-9144. ⟨10.1016/j.tet.2013.08.013⟩. ⟨hal-01798178⟩
24 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More