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Article Dans Une Revue ACS Catalysis Année : 2018

Selective Production of Propylene and 1-Butene from Ethylene by Catalytic Cascade Reactions

Résumé

In this study we report that ethylene can be simultaneously and selectively converted into propylene and 1-butene through one-pot catalytic cascade reactions. In a single continuous flow reactor, and under identical mild conditions (60 °C, 3 MPa), without the use of co-catalyst, ethylene was first dimerized/isomerized over Ni-AlKIT-6 catalysts to form butenes, which reacted then with the excess of ethylene over ReOx/Al2O3 to produce propylene and 1-butene with more than 86% total selectivity. The selectivity for 1-butene was 97.4% in the C4 fraction. The initial ethylene conversion was 73% and stabilized at 35% after 4 h on stream, with around 45% selectivity in propylene and 42% selectivity in 1-butene.
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hal-01745384 , version 1 (28-03-2018)

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Rémi Beucher, Radu Dorin Andrei, Claudia Cammarano, Anne Galarneau, Francois Fajula, et al.. Selective Production of Propylene and 1-Butene from Ethylene by Catalytic Cascade Reactions. ACS Catalysis, 2018, 8, pp.3636-3640. ⟨10.1021/acscatal.8b00663⟩. ⟨hal-01745384⟩
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