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Article Dans Une Revue Angewandte Chemie International Edition Année : 2018

Organometallic-Mediated Radical Polymerization of Vinylidene Fluoride

Résumé

An unprecedented level of control for the radical polymerization of vinylidene fluoride (VDF), yielding well‐defined PVDF (at least up to 14 500 g mol−1) with low dispersity (≤1.32), was achieved using organometallic‐mediated radical polymerization (OMRP) with an organocobalt compound as initiator. The high chain‐end fidelity was demonstrated by the synthesis of PVDF‐ and PVAc‐containing di‐and triblock copolymers. DFT calculations rationalize the efficient reactivation of both head and tail chain end dormant species.
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hal-01725498 , version 1 (01-03-2021)

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Sanjib Banerjee, Vincent Ladmiral, Antoine Debuigne, Christophe Detrembleur, Rinaldo Poli, et al.. Organometallic-Mediated Radical Polymerization of Vinylidene Fluoride. Angewandte Chemie International Edition, 2018, 57, pp.2934-2937. ⟨10.1002/anie.201712347⟩. ⟨hal-01725498⟩
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