A significant proportion of the Paris metro tunnels comprise a masonry vault built out of stone blocks and mortar joints, and sidewalls and slabs made of unreinforced concrete. In order to provide the necessary data for future structural evaluation, an extensive laboratory testing programme has been conducted to characterize the materials of the tunnel separately, i.e., mortar, stone, and concrete. The tests, carried out on specimens taken from cores extracted from a 1930s tunnel, enabled to determine the mechanical properties, including direct tensile, shear strength, and mode I fracture energy, as well as the properties of the stone-mortar interface. Results show that the masonry mortar joints could reach 10 cm in width, and that blocks of stone varied in composition and porosity, thus producing a wide range of mechanical properties. The concrete was composed of large-sized aggregates and showed low stiffness and strength. Based on these experimental results, ratios between mechanical characteristics are hereby proposed. Perspectives on the use of this experimental data in a finite element model are then discussed.