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Article Dans Une Revue Chemical Communications Année : 2017

The role of symmetry breaking in the structural trapping of light-induced excited spin states

Résumé

Light-Induced Excited Spin State Trapping (LIESST) data are reported for seven isostructural solvate salts from the iron(II)/2,6-di(pyrazol-1-yl)pyridine family. A complicated relationship between their spin-crossover T1/2 and T(LIESST) values may reflect low-temperature thermal and light-induced symmetry breaking, which is shown by one of the compounds but not by two others.
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hal-01662309 , version 1 (09-03-2021)

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Rafal Kulmaczewski, Elzbieta Trzop, Laurence J Kershaw Cook, Eric Collet, Guillaume Chastanet, et al.. The role of symmetry breaking in the structural trapping of light-induced excited spin states. Chemical Communications, 2017, 53 (99), pp.13268-13271. ⟨10.1039/c7cc07990g⟩. ⟨hal-01662309⟩
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