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Article Dans Une Revue Journal of Organic Chemistry Année : 2017

Lithium Amide Protected against Hydrolysis by Aggregated Lithium Halides: An MS + DFT Investigation

Résumé

Supported by mass spectrometry experiments, DFT computations indicate that the lithium amide of a 3-aminopyrrolidine (lithium benzhydryl(1-benzylpyrrolidin-3-yl)amide, 1-Li) is protected, up to a certain limit, against hydrolysis when it is aggregated with a strongly polar partner such as LiCl, LiBr, or MeLi.

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Chimie
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Dates et versions

hal-01639786 , version 1 (20-11-2017)

Identifiants

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Yves Gimbert, Denis Lesage, Catherine Fressigné, Jacques Maddaluno. Lithium Amide Protected against Hydrolysis by Aggregated Lithium Halides: An MS + DFT Investigation. Journal of Organic Chemistry, 2017, 82 (15), pp.8141-8147. ⟨10.1021/acs.joc.7b01419⟩. ⟨hal-01639786⟩
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