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Article Dans Une Revue Chemical Communications Année : 2017

Photoinduced reversible spin-state switching of an Fe III complex assisted by a halogen-bonded supramolecular network

Résumé

The organization of a molecular FeIII complex embedded in a halogen bonded 2D network is chemically tuned to trigger temperature- and light-induced spin-state switching. We attribute the associated magnetic properties and the unprecedented photoswitching effect to the optimized structural confinement provided by the presence of the supramolecular host framework.
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Dates et versions

hal-01596582 , version 1 (09-03-2018)

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Ie-Rang Jeon, Corine Mathonière, Rodolphe Clérac, Mathieu Rouzières, Olivier Jeannin, et al.. Photoinduced reversible spin-state switching of an Fe III complex assisted by a halogen-bonded supramolecular network. Chemical Communications, 2017, 53 (74), pp.10283-10286. ⟨10.1039/C7CC03797J⟩. ⟨hal-01596582⟩
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