Diastereoselective Michael additions to α,β-unsaturated α-sulfinyl phosphonates in the thiolane series - Archive ouverte HAL
Article Dans Une Revue Tetrahedron Letters Année : 2007

Diastereoselective Michael additions to α,β-unsaturated α-sulfinyl phosphonates in the thiolane series

Résumé

A chiral racemic 2-phosphono-2,3-didehydrothiolane sulfoxide was used as a Michael acceptor in the reactions with several nucleophiles, in particular thiols. In most cases the reactions were fully diastereoselective. The relative configuration of the resulting adducts was determined.

Domaines

Chimie inorganique Chimie de coordination Chimie organique

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https://hal.science/hal-01581424

Soumis le : lundi 4 septembre 2017-16:09:02

Dernière modification le : lundi 13 mai 2024-20:11:52

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Dates et versions

hal-01581424 , version 1 (04-09-2017)

Identifiants

Citer

Piotr Łyżwa, Aleksandra Jankowiak, Małgorzata Kwiatkowska, Marian Mikołajczyk, Piotr Kiełbasiński, et al.. Diastereoselective Michael additions to α,β-unsaturated α-sulfinyl phosphonates in the thiolane series. Tetrahedron Letters, 2007, 48 (3), pp.351 - 355. ⟨10.1016/j.tetlet.2006.11.098⟩. ⟨hal-01581424⟩

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