Carboxy-functionalized dithiolate di-iron complexes related to the active site of Fe-only hydrogenase - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of Organometallic Chemistry Année : 2007

Carboxy-functionalized dithiolate di-iron complexes related to the active site of Fe-only hydrogenase

Résumé

Reactions of the di-iron complex [Fe2(μ-S)2(CO)6]2− with carboxy-functionalized dihalide derivatives (XCH2)2R (X = Cl, R = NC6H4CH2CO2CH3; X = Br, R = C6H3COOH, C6H3COON(COCH2)2) gave new functionalized dithiolate di-iron complexes [Fe2(μ-SRS)(CO)6] (R = (CH2)2NC6H4CH2CO2CH3 (1), (CH2)2C6H3COOH (2), (CH2)2C6H3COON(COCH2)2 (3)) in low yields. The azadithiolate complex 1 has been characterized by a single crystal X-ray diffraction analysis and studied by electrochemical methods.

Domaines

Chimie

Dates et versions

hal-01581390 , version 1 (04-09-2017)

Identifiants

Citer

Vijendran Vijaikanth, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, et al.. Carboxy-functionalized dithiolate di-iron complexes related to the active site of Fe-only hydrogenase. Journal of Organometallic Chemistry, 2007, 692 (19), pp.4177 - 4181. ⟨10.1016/j.jorganchem.2007.06.042⟩. ⟨hal-01581390⟩
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