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Communication Dans Un Congrès Année : 2013

High spin <-> low spin ultrafast excitation and relaxation of an isolated iron(II) complex

Résumé

Picosecond and femtosecond time resolved pump-probe experiments make it possible to study both the low spin (LS) to high spin (HS) and high spin to low spin excitation and relaxation processes in the same isolated iron(II) complex. We demonstrate that both LS → HS and HS → LS can be recorded by changing the pump wavelength and occur on the same time scale.

Dates et versions

hal-01555674 , version 1 (04-07-2017)

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G. Gallé, J. Tribollet, Gediminas Jonusauskas, M. Tondusson, C. Mauriac, et al.. High spin <-> low spin ultrafast excitation and relaxation of an isolated iron(II) complex. XVIIIth International Conference on Ultrafast Phenomena, Jul 2012, Lausanne, Switzerland. ⟨10.1051/epjconf/20134105010⟩. ⟨hal-01555674⟩

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CNRS LOMA INC-CNRS
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