Spin-state modulation of molecular Fe III complexes via inclusion in halogen-bonded supramolecular networks

The cationic complex [Fe(qsal)] (Hqsal = N-(8-quinolyl)salicylaldimine) is encapsulated in anionic halogen-bonded 1D and 2D networks derived from sym-triiodotrifluorobenzene, [(CFI)Cl] and [(CFI)I]. Structural analysis and magnetic measurements show that the spin-state of this complex can be modulated by its inclusion in supramolecular host frameworks.

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Matériaux Chimie de coordination

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Spin-state modulation of molecular FeIII.pdf (921.38 Ko)

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https://hal.science/hal-01517775

Soumis le : jeudi 7 septembre 2017-09:47:08

Dernière modification le : mardi 22 octobre 2024-13:34:16

Dates et versions

hal-01517775 , version 1 (07-09-2017)

Identifiants

HAL Id : hal-01517775 , version 1
DOI : 10.1039/c7cc01943b
PUBMED : 28425508

Citer

Ie-Rang Jeon, Olivier Jeannin, Rodolphe Clérac, Mathieu Rouzières, Marc Fourmigué. Spin-state modulation of molecular Fe III complexes via inclusion in halogen-bonded supramolecular networks. Chemical Communications, 2017, 53 (36), pp.4989-4992. ⟨10.1039/c7cc01943b⟩. ⟨hal-01517775⟩

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