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                <term xml:lang="en"> Optical characterisation</term>
                <term xml:lang="en">Absorption</term>
                <term xml:lang="en"> ABS resins</term>
                <term xml:lang="en"> AFM</term>
                <term xml:lang="en"> Atomic force microscopy</term>
                <term xml:lang="en"> Heterojunctions</term>
                <term xml:lang="en"> Microscopic examination</term>
                <term xml:lang="en"> Poly[3-(4-octylphenoxy) thiophene]</term>
                <term xml:lang="en"> Organic polymers</term>
                <term xml:lang="en"> Photovoltaic</term>
                <term xml:lang="en"> Thiophene</term>
                <term xml:lang="en"> synthesis</term>
                <term xml:lang="en"> Sulfur compounds</term>
                <term xml:lang="en"> Solar energy</term>
                <term xml:lang="en"> Poly[3-(4-octyphenyl) thiophene]</term>
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              <p>Poly[3-(4-octylphenyl) thiophene] (PORT) and poly[3-(4-octylphenoxy) thiophene] (POPOT) with high head-to-tall regioregularitlis have been synthesised and photovoltaic properties have been investigated. POPT-blend-PCBM exhibits an interesting behaviour in bulk heterojunction whereas POPOT presents poor photovoltaic performances. UV-visible absorption and AFM images of the blends are presented to explain these results. Copyright © 2008 WILEY-VCH Verlag GmbH &amp; Co. KGaA.</p>
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