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Article Dans Une Revue Inorganic Chemistry Année : 2016

Room-Temperature Characterization of a Mixed-Valent µ-Hydroxodicopper(II,III) Complex

Résumé

Bis(μ-hydroxo)dicopper(II,II) bearing a naphthyridine-based ligand has been synthesized and characterized in the solid state and solution. Cyclic voltammetry at room temperature displays a reversible redox system that corresponds to the monoelectronic oxidation of the complex. Spectroscopic and time-resolved spectroelectrochemical data coupled to theoretical results support the formation of a charge-localized mixed-valent Cu II,III 2 species.
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hal-01475746 , version 1 (15-03-2023)

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James A Isaac, Franc A Gennarini, Isidoro López, Aurore Thibon-Pourret, Rolf David, et al.. Room-Temperature Characterization of a Mixed-Valent µ-Hydroxodicopper(II,III) Complex. Inorganic Chemistry, 2016, 55 (17), pp.8263-8266. ⟨10.1021/acs.inorgchem.6b01504⟩. ⟨hal-01475746⟩
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