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Article Dans Une Revue Chemical Communications Année : 2013

Flexibility of ZIF-8 materials studied using 129Xe NMR

Résumé

Structural changes in a porous hybrid inorganic–organic ZIF-8 compound have been explored using hyperpolarized 129Xe NMR of adsorbed xenon at various temperatures. Upon xenon adsorption at low temperature, the organic linkers undergo a reorientation leading to a stepwise increase in xenon adsorption and in chemical shift.

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Matériaux
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Dates et versions

hal-01468494 , version 1 (15-02-2017)

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Marie-Anne Springuel-Huet, Andrei Nossov, Flavien Guenneau, Antoine Gedeon. Flexibility of ZIF-8 materials studied using 129Xe NMR. Chemical Communications, 2013, 49 (67), pp.7403-7405. ⟨10.1039/c3cc43119c⟩. ⟨hal-01468494⟩
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