<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-01468417</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-09T04:33:27+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Optimized Sol–Gel Routes to Synthesize Yttria-Stabilized Zirconia Thin Films as Solid Electrolytes for Solid Oxide Fuel Cells</title>
            <author role="aut">
              <persName>
                <forename type="first">Émilie</forename>
                <surname>Courtin</surname>
              </persName>
              <idno type="halauthorid">682427-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Philippe</forename>
                <surname>Boy</surname>
              </persName>
              <idno type="halauthorid">855180-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Clément</forename>
                <surname>Rouhet</surname>
              </persName>
              <idno type="halauthorid">1140149-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Luc</forename>
                <surname>Bianchi</surname>
              </persName>
              <idno type="halauthorid">923562-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Eric</forename>
                <surname>Bruneton</surname>
              </persName>
              <idno type="halauthorid">30709-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Nathalie</forename>
                <surname>Poirot</surname>
              </persName>
              <email type="md5">f8a082fab0e55fa125d70a9bc76c16f3</email>
              <email type="domain">univ-tours.fr</email>
              <idno type="idhal" notation="string">nathalie-poirot</idno>
              <idno type="idhal" notation="numeric">20968</idno>
              <idno type="halauthorid" notation="string">39034-20968</idno>
              <idno type="IDREF">https://www.idref.fr/11360419X</idno>
              <affiliation ref="#struct-230940"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Christel</forename>
                <surname>Laberty-Robert</surname>
              </persName>
              <email type="md5">a5e4ad129d4d20c023b306039639f7ad</email>
              <email type="domain">sorbonne-universite.fr</email>
              <idno type="idhal" notation="string">christel-laberty</idno>
              <idno type="idhal" notation="numeric">174585</idno>
              <idno type="halauthorid" notation="string">416320-174585</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-3230-3164</idno>
              <idno type="IDREF">https://www.idref.fr/084148977</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/G-8847-2011</idno>
              <idno type="VIAF">https://viaf.org/viaf/189587694</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/G-8847-2011</idno>
              <affiliation ref="#struct-450674"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Clément</forename>
                <surname>Sanchez</surname>
              </persName>
              <email type="md5">06d572d5dc31f64606e4ba6a7ca8aad1</email>
              <email type="domain">upmc.fr</email>
              <idno type="idhal" notation="string">clement-sanchez</idno>
              <idno type="idhal" notation="numeric">181965</idno>
              <idno type="halauthorid" notation="string">6362-181965</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-6426-4844</idno>
              <idno type="IDREF">https://www.idref.fr/057595798</idno>
              <affiliation ref="#struct-450674"/>
              <affiliation ref="#struct-1059238"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Gestionnaire</forename>
                <surname>HAL-UPMC</surname>
              </persName>
              <email type="md5">5e5f92b30d5a5dc773d73b514d0dc0a4</email>
              <email type="domain">upmc.fr</email>
            </editor>
            <funder>Region Centre</funder>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2017-02-15 14:21:30</date>
              <date type="whenModified">2026-05-09 03:15:44</date>
              <date type="whenReleased">2017-02-15 14:21:30</date>
              <date type="whenProduced">2012-12</date>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="320703">
                <persName>
                  <forename>Gestionnaire</forename>
                  <surname>HAL-UPMC</surname>
                </persName>
                <email type="md5">5e5f92b30d5a5dc773d73b514d0dc0a4</email>
                <email type="domain">upmc.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-01468417</idno>
            <idno type="halUri">https://hal.science/hal-01468417</idno>
            <idno type="halBibtex">courtin:hal-01468417</idno>
            <idno type="halRefHtml">&lt;i&gt;Chemistry of Materials&lt;/i&gt;, 2012, 24 (23), pp.4540-4548. &lt;a target="_blank" href="https://dx.doi.org/10.1021/cm302177s"&gt;&amp;#x27E8;10.1021/cm302177s&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Chemistry of Materials, 2012, 24 (23), pp.4540-4548. &amp;#x27E8;10.1021/cm302177s&amp;#x27E9;</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="UPMC" corresp="SORBONNE-UNIVERSITE">Université Pierre et Marie Curie</idno>
            <idno type="stamp" n="UNIV-TOURS">Université François Rabelais</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="CDF">Collège de France</idno>
            <idno type="stamp" n="LCMCP" corresp="SORBONNE-UNIVERSITE">Laboratoire de Chimie de la Matière Condensée de Paris</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="LCMCP-MHN" corresp="LCMCP">Matériaux Hybrides et Nanomatériaux</idno>
            <idno type="stamp" n="PSL">Université Paris sciences et lettres</idno>
            <idno type="stamp" n="UPMC_POLE_2" corresp="UPMC">UPMC Pôle 2</idno>
            <idno type="stamp" n="GREMAN">Groupe de Recherche en Electronique, Matériaux, Acoustique et Nanotechnologies </idno>
            <idno type="stamp" n="INSA-GROUPE">Groupe INSA</idno>
            <idno type="stamp" n="SORBONNE-UNIVERSITE">Sorbonne Université</idno>
            <idno type="stamp" n="SU-INF-2018" corresp="SORBONNE-UNIVERSITE">SORBONNE université &lt;2018</idno>
            <idno type="stamp" n="SU-SCIENCES" corresp="SORBONNE-UNIVERSITE">Faculté des Sciences de Sorbonne Université</idno>
            <idno type="stamp" n="INSA-CVL">INSA CENTRE VAL DE LOIRE</idno>
            <idno type="stamp" n="CDF-PSL" corresp="PSL">Collège de France - PSL </idno>
            <idno type="stamp" n="ALLIANCE-SU"> Alliance Sorbonne Université</idno>
            <idno type="stamp" n="CHIMIE-SU" corresp="SORBONNE-UNIVERSITE">UFR de Chimie de Sorbonne-Université</idno>
            <idno type="stamp" n="ACADEMIE-SCIENCES">Académie des sciences</idno>
            <idno type="stamp" n="ACADEMIE-SCIENCES-PUBLICATIONS-MEMBRES" corresp="ACADEMIE-SCIENCES">Publications des membres, correspondants et associés étrangers de l'Académie des sciences</idno>
            <idno type="stamp" n="ACADEMIE-SCIENCES-PUBLICATIONS-MEMBRES-3" corresp="ACADEMIE-SCIENCES-PUBLICATIONS-MEMBRES">Publications des membres de l'Académie des sciences (lot 3)</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Optimized Sol–Gel Routes to Synthesize Yttria-Stabilized Zirconia Thin Films as Solid Electrolytes for Solid Oxide Fuel Cells</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Émilie</forename>
                    <surname>Courtin</surname>
                  </persName>
                  <idno type="halauthorid">682427-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Philippe</forename>
                    <surname>Boy</surname>
                  </persName>
                  <idno type="halauthorid">855180-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Clément</forename>
                    <surname>Rouhet</surname>
                  </persName>
                  <idno type="halauthorid">1140149-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Luc</forename>
                    <surname>Bianchi</surname>
                  </persName>
                  <idno type="halauthorid">923562-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Eric</forename>
                    <surname>Bruneton</surname>
                  </persName>
                  <idno type="halauthorid">30709-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Nathalie</forename>
                    <surname>Poirot</surname>
                  </persName>
                  <email type="md5">f8a082fab0e55fa125d70a9bc76c16f3</email>
                  <email type="domain">univ-tours.fr</email>
                  <idno type="idhal" notation="string">nathalie-poirot</idno>
                  <idno type="idhal" notation="numeric">20968</idno>
                  <idno type="halauthorid" notation="string">39034-20968</idno>
                  <idno type="IDREF">https://www.idref.fr/11360419X</idno>
                  <affiliation ref="#struct-230940"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Christel</forename>
                    <surname>Laberty-Robert</surname>
                  </persName>
                  <email type="md5">a5e4ad129d4d20c023b306039639f7ad</email>
                  <email type="domain">sorbonne-universite.fr</email>
                  <idno type="idhal" notation="string">christel-laberty</idno>
                  <idno type="idhal" notation="numeric">174585</idno>
                  <idno type="halauthorid" notation="string">416320-174585</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-3230-3164</idno>
                  <idno type="IDREF">https://www.idref.fr/084148977</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/G-8847-2011</idno>
                  <idno type="VIAF">https://viaf.org/viaf/189587694</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/G-8847-2011</idno>
                  <affiliation ref="#struct-450674"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Clément</forename>
                    <surname>Sanchez</surname>
                  </persName>
                  <email type="md5">06d572d5dc31f64606e4ba6a7ca8aad1</email>
                  <email type="domain">upmc.fr</email>
                  <idno type="idhal" notation="string">clement-sanchez</idno>
                  <idno type="idhal" notation="numeric">181965</idno>
                  <idno type="halauthorid" notation="string">6362-181965</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-6426-4844</idno>
                  <idno type="IDREF">https://www.idref.fr/057595798</idno>
                  <affiliation ref="#struct-450674"/>
                  <affiliation ref="#struct-1059238"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">11637</idno>
                <idno type="issn">0897-4756</idno>
                <idno type="eissn">1520-5002</idno>
                <title level="j">Chemistry of Materials</title>
                <imprint>
                  <publisher>American Chemical Society</publisher>
                  <biblScope unit="volume">24</biblScope>
                  <biblScope unit="issue">23</biblScope>
                  <biblScope unit="pp">4540-4548</biblScope>
                  <date type="datePub">2012-12</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1021/cm302177s</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en"> thin films</term>
                <term xml:lang="en">thin films</term>
                <term xml:lang="en">sol-gel</term>
                <term xml:lang="en">solid oxide fuel cells</term>
                <term xml:lang="en">fuel cell performance</term>
                <term xml:lang="en">electrolyte</term>
                <term xml:lang="en"> fuel cell performance</term>
                <term xml:lang="en"> sol-gel</term>
              </keywords>
              <classCode scheme="halDomain" n="chim.mate">Chemical Sciences/Material chemistry</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Sol–gel strategies are carefully evaluated and compared to synthesize electrolyte materials for Intermediate Temperature SOFCs (Solid Oxide Fuel Cells). Robust 10–20 μm thick cubic Yttria-Stabilized Zirconia (YSZ), (Y2O3)0.08(ZrO2)0.92, films have been prepared by using nanocomposite stable sols composed with “sol–gel made” YSZ binders and YSZ powder. Two different strategies have been investigated for the synthesis of 8YSZ binders: a mixed alkoxide-nitrate route in alcoholic media, and an environment-friendly hydrothermal route, in water media. Ionic conductivities of ∼2.5 × 10–2 S cm–1 are obtained at 800 °C for powders made by the hydrothermal and the alkoxide routes. Films synthesized from composite sols that contain commercial YSZ powder and the organic binder or the water-based binder, have been deposited on YSZ-NiO cermets and integrated in an entire single fuel cell. The two optimized routes yield to gastight YSZ electrolytes. In particular with the organic-based binder, a maximum power density of 250 mW cm–2 at 850 °C has been achieved. The proposed route can be extended to other materials for different applications such as ferroelectric and dielectric materials.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-230940" status="VALID">
          <idno type="IdRef">228797675</idno>
          <idno type="RNSR">201220242E</idno>
          <idno type="ROR">https://ror.org/051qnm298</idno>
          <orgName>GREMAN (matériaux, microélectronique, acoustique et nanotechnologies)</orgName>
          <orgName type="acronym">GREMAN</orgName>
          <date type="start">2012-01-01</date>
          <desc>
            <address>
              <addrLine>Bât. E, 20 avenue Monge, 37200 Tours</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://greman.univ-tours.fr</ref>
          </desc>
          <listRelation>
            <relation active="#struct-300298" type="direct"/>
            <relation active="#struct-303079" type="direct"/>
            <relation active="#struct-301232" type="indirect"/>
            <relation name="UMR7347" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="researchteam" xml:id="struct-450674" status="OLD">
          <orgName>Matériaux Hybrides et Nanomatériaux</orgName>
          <orgName type="acronym">MHN</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-237043" type="direct"/>
            <relation active="#struct-93591" type="indirect"/>
            <relation active="#struct-300026" type="indirect"/>
            <relation active="#struct-341038" type="indirect"/>
            <relation name="UMR7574" active="#struct-441569" type="indirect"/>
          </listRelation>
        </org>
        <org type="researchteam" xml:id="struct-1059238" status="OLD">
          <orgName>Chaire Chimie des matériaux hybrides</orgName>
          <date type="start">2011-02-10</date>
          <date type="end">2020-12-31</date>
          <desc>
            <address>
              <addrLine>11 place Marcelin Berthelot 75005 PARIS</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.college-de-france.fr/site/clement-sanchez/index.htm</ref>
          </desc>
          <listRelation>
            <relation active="#struct-542010" type="direct"/>
            <relation active="#struct-341038" type="indirect"/>
            <relation active="#struct-413221" type="indirect"/>
            <relation name="UMR7574" active="#struct-441569" type="indirect"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-300298" status="VALID">
          <idno type="IdRef">026404478</idno>
          <idno type="ISNI">0000000121608742</idno>
          <idno type="ROR">https://ror.org/02wwzvj46</idno>
          <orgName>Université de Tours</orgName>
          <orgName type="acronym">UT</orgName>
          <date type="start">1970-12-17</date>
          <desc>
            <address>
              <addrLine>60 rue du Plat d'Étain, 37020 Tours cedex 1</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-tours.fr</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-303079" status="VALID">
          <idno type="IdRef">203592077</idno>
          <orgName>Institut National des Sciences Appliquées - Centre Val de Loire</orgName>
          <orgName type="acronym">INSA CVL</orgName>
          <date type="start">2014-01-01</date>
          <desc>
            <address>
              <addrLine>88 boulevard Lahitolle, CS 60013, 18022 Bourges cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.insa-centrevaldeloire.fr/fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-301232" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-301232" status="VALID">
          <idno type="IdRef">162105150</idno>
          <orgName>Institut National des Sciences Appliquées</orgName>
          <orgName type="acronym">INSA</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="laboratory" xml:id="struct-237043" status="OLD">
          <idno type="IdRef">240311051</idno>
          <idno type="ISNI">0000 0004 0369 7931</idno>
          <idno type="RNSR">199712620K</idno>
          <idno type="ROR">https://ror.org/028ta1f94</idno>
          <orgName>Laboratoire de Chimie de la Matière Condensée de Paris</orgName>
          <orgName type="acronym">LCMCP</orgName>
          <date type="start">1997-01-01</date>
          <date type="end">2017-12-31</date>
          <desc>
            <address>
              <addrLine>11 place Marcelin Berthelot 75231 Paris Cedex 05</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.labos.upmc.fr/lcmcp</ref>
          </desc>
          <listRelation>
            <relation active="#struct-93591" type="direct"/>
            <relation active="#struct-300026" type="direct"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR7574" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-93591" status="OLD">
          <idno type="ROR">https://ror.org/02en5vm52</idno>
          <orgName>Université Pierre et Marie Curie - Paris 6</orgName>
          <orgName type="acronym">UPMC</orgName>
          <date type="end">2017-12-31</date>
          <desc>
            <address>
              <addrLine>4 place Jussieu - 75005 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.upmc.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-300026" status="VALID">
          <orgName>Collège de France</orgName>
          <orgName type="acronym">CdF (institution)</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="laboratory" xml:id="struct-542010" status="VALID">
          <idno type="IdRef">240311051</idno>
          <idno type="ISNI">0000 0004 0369 7931</idno>
          <idno type="RNSR">199712620K</idno>
          <idno type="ROR">https://ror.org/028ta1f94</idno>
          <orgName>Laboratoire de Chimie de la Matière Condensée de Paris</orgName>
          <orgName type="acronym">LCMCP</orgName>
          <date type="start">2014-01-01</date>
          <desc>
            <address>
              <addrLine>Sorbonne Université4 place Jussieu75252 Paris cedex 05</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.labos.upmc.fr/lcmcp</ref>
          </desc>
          <listRelation>
            <relation active="#struct-341038" type="direct"/>
            <relation active="#struct-413221" type="direct"/>
            <relation name="UMR7574" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-413221" status="VALID">
          <idno type="IdRef">221333754</idno>
          <idno type="ROR">https://ror.org/02en5vm52</idno>
          <orgName>Sorbonne Université</orgName>
          <orgName type="acronym">SU</orgName>
          <date type="start">2018-01-01</date>
          <desc>
            <address>
              <addrLine>21 rue de l’École de médecine - 75006 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.sorbonne-universite.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>