Intermolecular radical 1,2-addition of the BlocBuilder MA alkoxyamine onto activated olefins: a versatile tool for the synthesis of complex macromolecular architecture - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Polymer Chemistry Année : 2011

Intermolecular radical 1,2-addition of the BlocBuilder MA alkoxyamine onto activated olefins: a versatile tool for the synthesis of complex macromolecular architecture

Pierre-Emmanuel Dufils
  • Fonction : Auteur
Denis Bertin
Catherine Lefay
Yohann Guillaneuf
Didier Gigmes

Résumé

This review described the potential of the intermolecular radical 1,2-addition from the commercially available BlocBuilder MA alkoxyamine onto activated olefins to synthesize either new functionalized alkoxyamines or various macromolecular architectures. Following this approach, diblock, triblock copolymers, star polymers and hybrid materials are then easily prepared. The various applications of such architectures will be briefly reviewed. Interestingly this new synthetic tool widely expands the range of complex macromolecular architectures which could be obtained by the nitroxide-mediated polymerization (NMP) process.

Domaines

Chimie
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Dates et versions

hal-01460322 , version 1 (07-02-2017)

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Citer

Pierre-Emmanuel Dufils, David Glé, Denis Bertin, Catherine Lefay, Yohann Guillaneuf, et al.. Intermolecular radical 1,2-addition of the BlocBuilder MA alkoxyamine onto activated olefins: a versatile tool for the synthesis of complex macromolecular architecture. Polymer Chemistry, 2011, 2 (8), pp.1624--1631. ⟨10.1039/C1PY00057H⟩. ⟨hal-01460322⟩
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