Symmetry breaking above room temperature in an Fe(ii) spin crossover complex with an N4O2 donor set. - Archive ouverte HAL
Article Dans Une Revue Chemical Communications Année : 2017

Symmetry breaking above room temperature in an Fe(ii) spin crossover complex with an N4O2 donor set.

Résumé

[Fe(qsal-Cl)2] is one of the few known Fe(ii) spin crossover compounds with an N4O2 donor atom environment. It shows an abrupt two-step spin transition at 308 and 316 K and importantly, symmetry breaking at the highest temperature reported, to date, in spin crossover compounds.
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Dates et versions

hal-01453351 , version 1 (22-01-2021)

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Citer

Wasinee Phonsri, Casey G. Davies, Guy N. L. Jameson, Boujemaa Moubaraki, Jas S. Ward, et al.. Symmetry breaking above room temperature in an Fe(ii) spin crossover complex with an N4O2 donor set.. Chemical Communications, 2017, 53 (8), pp.1374-1377. ⟨10.1039/c6cc10040f⟩. ⟨hal-01453351⟩
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