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Article Dans Une Revue Electrochimica Acta Année : 2015

Synthesis and characterization of Lindqvist-type polyoxometalate–porphyrin copolymers

Résumé

Hybrid polyoxometalate-porphyrin copolymeric films were obtained by the electrooxidation of 5, 15-ditolyl porphyrin (H2T2P) and zinc-β-octaethylporphyrin (ZnOEP) in the presence of the Lindqvist-type polyoxovanadates TBA2[V6O13{(OCH2)3CNHCO(4-C5H4N)}2] (Py-POM-Py). The resulting films have been characterized by UV–visible absorption spectroscopy, X-ray photoelectron spectroscopy, atomic force microscopy and electrochemistry. Electrochemical quartz crystal microbalance was employed to investigate the copolymer mass.

Domaines

Chimie Matériaux
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Dates et versions

hal-01445580 , version 1 (25-01-2017)

Identifiants

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Zhaohui Huo, Zang Dejin, Yang Shu, Rana Farha, Michel Goldmann, et al.. Synthesis and characterization of Lindqvist-type polyoxometalate–porphyrin copolymers . Electrochimica Acta, 2015, 179, pp.326-335. ⟨10.1016/j.electacta.2015.03.178⟩. ⟨hal-01445580⟩
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